404 research outputs found
Importance relative des differentes fractions cellulaires dans la synthese hepatique des acides gras in vivo
AbstractThe synthesis of fatty acids in mitochondria, microsomes and supernatant of mice liver was studied after administration of glucose 14C or 3H, acetate 14C or 3H and pyruvate 14C.The results suggest that the cellular structures corresponding to the microsomes are the major site of fatty acid synthesis in the liver in vivo
Optimization methods and their use in low-energy electron-diffraction calculations
The speed of automatic optimization procedures used in surface structure determination by low-energy electron diffraction can be greatly enhanced by the use of linear approximations in the calculation of scattering amplitudes. It is shown how linear approximations can be used in the calculation of derivatives of intensities which are required in the least-squares optimization method. The derivatives with respect to structural and nonstructural parameters are calculated applying a combination of analytic and numerical methods in connection with approximations of the sum over lattice points in the angular momentum representation. Special cases for different structural and nonstructural parameters and simplifications for special geometries are discussed. The computational effort becomes nearly independent of the number of free parameters and enables the analysis of complex surface structures
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John Pendry: His Contributions to the Development of LEED Surface Crystallography
In this paper we discuss the pivotal role played by Sir John Pendry in the development of Low Energy Electron Diffraction (LEED) during the past three decades; the earliest understanding on the physics of LEED to the development of sophisticated methods for the structural solution of complex surfaces
Manifestation of quantum chaos on scattering techniques: application to low-energy and photo-electron diffraction intensities
Intensities of LEED and PED are analyzed from a statistical point of view.
The probability distribution is compared with a Porter-Thomas law,
characteristic of a chaotic quantum system. The agreement obtained is
understood in terms of analogies between simple models and Berry's conjecture
for a typical wavefunction of a chaotic system. The consequences of this
behaviour on surface structural analysis are qualitatively discussed by looking
at the behaviour of standard correlation factors.Comment: 5 pages, 4 postscript figures, Latex, APS,
http://www.icmm.csic.es/Pandres/pedro.ht
Ratchet Effect in Surface Electromigration: Smoothing Surfaces by an ac Field
We demonstrate that for surfaces that have a nonzero Schwoebel barrier the
application of an ac field parallel to the surface induces a net electro-
migration current that points in the descending step direction. The magnitude
of the current is calculated analytically and compared with Monte Carlo
simulations. Since a downhill current smoothes the surface, our results imply
that the application of ac fields can aid the smoothing process during
annealing and can slow or eliminate the Schwoebel-barrier-induced mound
formation during growth.Comment: 4 pages, LaTeX, 4 ps figure
Efficient determiniation of multilayer relaxation in the Pt(210) stepped and densely kinked surface
The multilayer relaxation of the Pt(210) stepped and kinked surface is analyzed by low-energy-electron diffraction. This is the first application of the new real-space multiple-scattering theory of LEED, designed specifically for such open surfaces where conventional theories fail. Combined with an automated tensor LEED method, it efficiently detects nonalternating atomic relaxations which are oriented primarily perpendicular to the surface. These relaxations are in qualitative agreement with new embedded-atom-method results
The Static and Dynamic Lattice Changes Induced by Hydrogen Adsorption on NiAl(110)
Static and dynamic changes induced by adsorption of atomic hydrogen on the
NiAl(110) lattice at 130 K have been examined as a function of adsorbate
coverage. Adsorbed hydrogen exists in three distinct phases. At low coverages
the hydrogen is itinerant because of quantum tunneling between sites and
exhibits no observable vibrational modes. Between 0.4 ML and 0.6 ML, substrate
mediated interactions produce an ordered superstructure with c(2x2) symmetry,
and at higher coverages, hydrogen exists as a disordered lattice gas. This
picture of how hydrogen interacts with NiAl(110) is developed from our data and
compared to current theoretical predictions.Comment: 36 pages, including 12 figures, 2 tables and 58 reference
LEED Holography applied to a complex superstructure: a direct view of the adatom cluster on SiC(111)-(3x3)
For the example of the SiC(111)-(3x3) reconstruction we show that a
holographic interpretation of discrete Low Energy Electron Diffraction (LEED)
spot intensities arising from ordered, large unit cell superstructures can give
direct access to the local geometry of a cluster around an elevated atom,
provided there is only one such prominent atom per surface unit cell. By
comparing the holographic images obtained from experimental and calculated data
we illuminate validity, current limits and possible shortcomings of the method.
In particular, we show that periodic vacancies such as cornerholes may inhibit
the correct detection of the atomic positions. By contrast, the extra
diffraction intensity due to slight substrate reconstructions, as for example
buckling, seems to have negligible influence on the images. Due to the spatial
information depth of the method the stacking of the cluster can be imaged down
to the fourth layer. Finally, it is demonstrated how this structural knowledge
of the adcluster geometry can be used to guide the dynamical intensity analysis
subsequent to the holographic reconstruction and necessary to retrieve the full
unit cell structure.Comment: 11 pages RevTex, 6 figures, Phys. Rev. B in pres
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