404 research outputs found

    Importance relative des differentes fractions cellulaires dans la synthese hepatique des acides gras in vivo

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    AbstractThe synthesis of fatty acids in mitochondria, microsomes and supernatant of mice liver was studied after administration of glucose 14C or 3H, acetate 14C or 3H and pyruvate 14C.The results suggest that the cellular structures corresponding to the microsomes are the major site of fatty acid synthesis in the liver in vivo

    Optimization methods and their use in low-energy electron-diffraction calculations

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    The speed of automatic optimization procedures used in surface structure determination by low-energy electron diffraction can be greatly enhanced by the use of linear approximations in the calculation of scattering amplitudes. It is shown how linear approximations can be used in the calculation of derivatives of intensities which are required in the least-squares optimization method. The derivatives with respect to structural and nonstructural parameters are calculated applying a combination of analytic and numerical methods in connection with approximations of the sum over lattice points in the angular momentum representation. Special cases for different structural and nonstructural parameters and simplifications for special geometries are discussed. The computational effort becomes nearly independent of the number of free parameters and enables the analysis of complex surface structures

    Manifestation of quantum chaos on scattering techniques: application to low-energy and photo-electron diffraction intensities

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    Intensities of LEED and PED are analyzed from a statistical point of view. The probability distribution is compared with a Porter-Thomas law, characteristic of a chaotic quantum system. The agreement obtained is understood in terms of analogies between simple models and Berry's conjecture for a typical wavefunction of a chaotic system. The consequences of this behaviour on surface structural analysis are qualitatively discussed by looking at the behaviour of standard correlation factors.Comment: 5 pages, 4 postscript figures, Latex, APS, http://www.icmm.csic.es/Pandres/pedro.ht

    Ratchet Effect in Surface Electromigration: Smoothing Surfaces by an ac Field

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    We demonstrate that for surfaces that have a nonzero Schwoebel barrier the application of an ac field parallel to the surface induces a net electro- migration current that points in the descending step direction. The magnitude of the current is calculated analytically and compared with Monte Carlo simulations. Since a downhill current smoothes the surface, our results imply that the application of ac fields can aid the smoothing process during annealing and can slow or eliminate the Schwoebel-barrier-induced mound formation during growth.Comment: 4 pages, LaTeX, 4 ps figure

    Efficient determiniation of multilayer relaxation in the Pt(210) stepped and densely kinked surface

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    The multilayer relaxation of the Pt(210) stepped and kinked surface is analyzed by low-energy-electron diffraction. This is the first application of the new real-space multiple-scattering theory of LEED, designed specifically for such open surfaces where conventional theories fail. Combined with an automated tensor LEED method, it efficiently detects nonalternating atomic relaxations which are oriented primarily perpendicular to the surface. These relaxations are in qualitative agreement with new embedded-atom-method results

    The Static and Dynamic Lattice Changes Induced by Hydrogen Adsorption on NiAl(110)

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    Static and dynamic changes induced by adsorption of atomic hydrogen on the NiAl(110) lattice at 130 K have been examined as a function of adsorbate coverage. Adsorbed hydrogen exists in three distinct phases. At low coverages the hydrogen is itinerant because of quantum tunneling between sites and exhibits no observable vibrational modes. Between 0.4 ML and 0.6 ML, substrate mediated interactions produce an ordered superstructure with c(2x2) symmetry, and at higher coverages, hydrogen exists as a disordered lattice gas. This picture of how hydrogen interacts with NiAl(110) is developed from our data and compared to current theoretical predictions.Comment: 36 pages, including 12 figures, 2 tables and 58 reference

    LEED Holography applied to a complex superstructure: a direct view of the adatom cluster on SiC(111)-(3x3)

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    For the example of the SiC(111)-(3x3) reconstruction we show that a holographic interpretation of discrete Low Energy Electron Diffraction (LEED) spot intensities arising from ordered, large unit cell superstructures can give direct access to the local geometry of a cluster around an elevated atom, provided there is only one such prominent atom per surface unit cell. By comparing the holographic images obtained from experimental and calculated data we illuminate validity, current limits and possible shortcomings of the method. In particular, we show that periodic vacancies such as cornerholes may inhibit the correct detection of the atomic positions. By contrast, the extra diffraction intensity due to slight substrate reconstructions, as for example buckling, seems to have negligible influence on the images. Due to the spatial information depth of the method the stacking of the cluster can be imaged down to the fourth layer. Finally, it is demonstrated how this structural knowledge of the adcluster geometry can be used to guide the dynamical intensity analysis subsequent to the holographic reconstruction and necessary to retrieve the full unit cell structure.Comment: 11 pages RevTex, 6 figures, Phys. Rev. B in pres
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